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Free, publicly-accessible full text available September 1, 2026
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Hao, Mingwei; Yang, Jonghee; Yu, Wenjian; Lawrie, Benjamin J; Guo, Pengfei; Zhang, Xiangzhao; Duan, Tianwei; Xiao, Tong; Chen, Linqi; Xiang, Yang; et al (, Nature Nanotechnology)Free, publicly-accessible full text available February 24, 2026
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Xiao, Tong; Hao, Mingwei; Duan, Tianwei; Li, Yanyan; Zhang, Yalan; Guo, Peijun; Zhou, Yuanyuan (, Nature Energy)
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Duan, Tianwei; You, Shuai; Chen, Min; Yu, Wenjian; Li, Yanyan; Guo, Peijun; Berry, Joseph J; Luther, Joseph M; Zhu, Kai; Zhou, Yuanyuan (, Science)Mechanical failure and chemical degradation of device heterointerfaces can strongly influence the long-term stability of perovskite solar cells (PSCs) under thermal cycling and damp heat conditions. We report chirality-mediated interfaces based onR-/S-methylbenzyl-ammonium between the perovskite absorber and electron-transport layer to create an elastic yet strong heterointerface with increased mechanical reliability. This interface harnesses enantiomer-controlled entropy to enhance tolerance to thermal cycling–induced fatigue and material degradation, and a heterochiral arrangement of organic cations leads to closer packing of benzene rings, which enhances chemical stability and charge transfer. The encapsulated PSCs showed retentions of 92% of power-conversion efficiency under a thermal cycling test (−40°C to 85°C; 200 cycles over 1200 hours) and 92% under a damp heat test (85% relative humidity; 85°C; 600 hours).more » « less
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